Titanium & Advanced Metals

K94610 Supply Detail

Category

  • Bar and Rod

  • Plate and Sheet

  • Strip

  • Pipe and Tube

  • Wire

  • Welding

  • Powder Material

  • Cast Products

  • Forged Products

  • Fittings

  • Fastening

    Forms & Sizes

    Round Bar:
    φ2–500 mm, 1–6 m length

    Flat/Square Bar:
    4–100 mm thickness/width

    Hex Bar:
    A/F 3–100 mm

    Hollow Bar:
    OD 20–300 mm

    Forms & Sizes

    Sheet:
    0.3–6 mm thickness

    Medium Plate:
    6–25 mm thickness

    Heavy Plate:
    25–100 mm thickness

    Forms & Sizes

    Standard Strip:
    0.05–3 mm thick,
    10–600 mm wide

    Precision strip:
    0.01–0.5 mm thick,
    tight tolerance ±0.005 mm

    Foil:
    0.005–0.1 mm thick

    Forms & Sizes

    Seamless Tube:
    OD 6–450 mm,
    WT 1–50 mm,
    1–12 m length

    Welded Tube:
    OD 10–600 mm,
    WT 1–20 mm

    Capillary Tube:
    OD 1–10 mm,
    WT 0.1–2 mm

    Forms & Sizes

    Wire Form:
    Cold Drawn Wire,
    Bright Wire,
    Spring Wire,
    Fine Wire,
    Ultra-fine Wire

    General Diameter:
    φ0.1–10 mm

    Coil Weight:
    50–500 kg,
    customizable tolerance

    Forms & Sizes

    Solid Wire:
    φ0.8–4.0 mm

    Flux-cored Wire:
    φ1.2–4.0 mm

    Welding Rod:
    φ2.0–5.0 mm

    Forms & Sizes

    Powder Form:
    AM 3D Printing Powder,
    Spherical Powder,
    Gas-atomized Powder,
    Water-atomized Powder

    Particle Size:
    10–150 μm

    Sphericity:
    ≥90% for AM grade

    Forms & Sizes

    Cast Ingot:
    φ200–800 mm

    Precision Casting:
    min wall 0.5 mm

    Cast Pipe:
    OD 100–600 mm,
    WT 10–50 mm

    Forms & Sizes

    Forged Bar:
    Φ35–500 mm

    Forged Ring:
    OD 200–2000 mm

    Forging Weight:
    1–5000 kg

    Forms & Sizes

    Fittings Form:
    Elbow, Tee, Reducer, Flange, Cap, Outlet, Lap Joint

    Size range:
    1/2''–24'' (DN15–DN600)

    Wall thickness:
    Sch10–Sch160, STD, XS, XXS

    Pressure Class:
    150–2500 LB

    Forms & Sizes

    Fastening Form:
    Bolt, Nut, Screw, Stud, Washer, Pin, Rivet

    Metric: M3–M64

    Imperial: #4–2.5''

    Length: 6–500 mm

K94610 Product Description

Overview

K94610 is an iron–nickel–cobalt controlled-expansion alloy (nominally Fe-29Ni-17Co) designed to have substantially the same thermal-expansion characteristics as borosilicate glass, so that a tight, hermetic mechanical joint can be maintained between metal and glass over a wide temperature range. This datasheet presents the material within the American (ASTM / UNS) standard system.

Most metals cannot be sealed directly to glass because their coefficient of thermal expansion differs from glass; as a joint cools, the mismatch cracks the seal. This alloy has a low expansion coefficient — about 5 ppm/K between 30 and 200 °C, rising toward ~10 ppm/K near 800 °C — that closely matches borosilicate (e.g. Pyrex) glasses and alumina ceramics. Its non-linear expansion curve can be tailored to a given glass so the joint tolerates a wide temperature range. Chemically it bonds to glass through an intermediate nickel-oxide/cobalt-oxide layer; the cobalt makes the oxide easier to melt and dissolve into the molten glass, and a grey to grey-blue surface indicates a good seal.

It is used wherever a reliable hermetic glass-to-metal or ceramic-to-metal seal is required: electronic-package bodies and bases, transistor and integrated-circuit headers and lead frames, vacuum-tube and microwave-device components, submounts in microelectronics, and material transitions in vacuum chambers. The alloy is readily fabricated and welded, and forms its sealing oxide on controlled oxidation prior to glass sealing.

1. Physical Properties

Values per manufacturer / reference data, annealed condition.

Property Value Unit
Density 8.36 g/cm³
Melting point ~1450 °C
Young's modulus (20 °C) 138 GPa
Thermal conductivity (20 °C) 17.3 W/m·K
Coefficient of thermal expansion (30–200 °C) ~5.1 µm/m·°C
Coefficient of thermal expansion (to ~800 °C) ~10 µm/m·°C
Curie temperature ~435 °C
Electrical resistivity (20 °C) 0.49 µΩ·m
Inflection (curve) temperature ~450 °C

2. Chemical Composition (Limiting, wt %)

Limiting composition per ASTM F15 (UNS K94610).

Element Symbol Min % Max % Role in Alloy
Iron Fe Balance (~54) Base element
Nickel Ni 28.0 30.0 Controls low thermal expansion
Cobalt Co 17.0 18.0 Controls expansion + glass-bonding oxide
Manganese Mn 0.30 Deoxidiser
Silicon Si 0.20 Deoxidiser
Carbon C 0.02 Very low
Aluminium Al 0.10 Residual
Magnesium Mg 0.10 Residual

Nominal: Fe-29Ni-17Co. The balanced Ni+Co content sets the low, glass-matched expansion; the cobalt also aids formation of the NiO/CoO oxide layer that bonds to glass.

3. Mechanical Properties

Typical room-temperature properties, annealed condition.

Property Value Source
Ultimate tensile strength ~515–550 MPa Annealed
0.2% proof strength (yield) ~340–380 MPa Annealed
Elongation at break ~30 % Annealed
Hardness ~70–80 HRB Annealed

The alloy is selected for its thermal-expansion and sealing behaviour rather than for structural strength. It can be cold-worked to raise strength. Values are typical; confirm against the mill test certificate.

4. Thermal-Expansion and Sealing Behaviour

Property Performance Notes
Glass-to-metal sealing Excellent Matches borosilicate (Pyrex) glass
Ceramic-to-metal sealing Excellent Matches alumina ceramics
Expansion match Excellent ~5 ppm/K (30–200 °C); tailorable non-linear curve
Hermeticity Excellent Reliable hermetic seals
Oxide-layer bonding Excellent NiO/CoO layer; cobalt aids dissolution into glass
Atmospheric corrosion Moderate Plate (e.g. Ni/Au) for corrosion/solder service
Oxidising acids Poor Not a corrosion-service alloy

5. Heat Treatment

A controlled-expansion Fe-Ni-Co alloy; not age-hardenable. Heat treatment is for annealing / stress relief and for oxide conditioning prior to glass sealing.

Anneal / stress relief Bright (hydrogen) anneal or vacuum anneal per manufacturer guidance to stabilise dimensions and expansion behaviour and remove cold-work stresses.

Oxidation before sealing A controlled oxidation is applied to develop the correct NiO/CoO oxide layer for glass bonding; oxide thickness and character strongly affect seal strength. A grey to grey-blue sealed surface indicates a sound seal.

6. Weldability and Joining

Readily welded (resistance, laser and arc methods), brazed and soldered, and routinely sealed to glass and ceramic. For solder and corrosion service it is usually plated (e.g. nickel and/or gold).

Process Applicability Notes
Resistance / laser welding Excellent Common for packages and leads
Brazing / soldering Good Often after Ni/Au plating
Glass-to-metal sealing Primary use Controlled oxidation first

Cleanliness and correct oxide conditioning are critical to hermetic-seal quality.

7. Machinability and Fabrication

Machining / Fabrication Guidelines

Parameter Recommendation
Machinability Machinable with conventional tooling; work-hardens
Forms Strip, wire, sheet, rod, tube — for stamping/forming leads and bodies
Plating Ni/Au plating common for solderability/corrosion
Coolant Flood coolant recommended

Forming Processes

Process Notes
Cold forming / stamping Readily formed into headers, lead frames, eyelets
Annealing Bright/vacuum anneal to stabilise expansion
Oxidation Controlled oxide before glass sealing

8. Applications

Industry Typical Components Key Requirements
Electronics packaging IC and transistor headers, package bodies/bases, lead frames Hermetic glass-to-metal seal; expansion match
Microelectronics Submounts, compensation plates Expansion match; stress compensation
Vacuum / microwave Vacuum-tube parts, microwave-device components, feedthroughs Hermetic seal; vacuum integrity
Optoelectronics Laser-diode and sensor packages Hermetic ceramic/glass seal
Aerospace / sensors Hermetic connectors and feedthroughs Reliable seals over temperature

9. Available Product Forms and Standards (ASTM / UNS System)

Product Form Standard Notes
Strip, sheet and plate ASTM F15 Glass-sealing grade
Wire and rod ASTM F15 Leads / feedthroughs
Tube ASTM F15
Forgings / machined parts UNS K94610

Iron-nickel-cobalt controlled-expansion (glass-sealing) alloy. UNS K94610; ASTM F15. Tradenames include Kovar, Nilo K, Rodar, Dilvar P1.

10. Comparison with Related Alloys (UNS System)

UNS Nominal CTE (ppm/K) Best Used For
K94610 Fe-29Ni-17Co ~5.1 Matches borosilicate glass + alumina
K94100 Fe-42Ni ~4.5–5.3 Lead frames; soft glass / ceramic seals
K93603 Fe-36Ni ~1.3 Lowest expansion; precision (not glass)
K94052 Fe-51Ni ~10 Soft-glass sealing (higher expansion)
Fe-Ni + Cu clad matched Lamp lead-in wire glass sealing

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